FINAL REGULATIONS GOVERNING BROWNFIELD VOLUNTARY CLEANUP AND REDEVELOPMENT IN MISSISSIPPI


Table of Contents

SUBPART I. GENERAL REQUIREMENTS Chapter 1. GENERAL Chapter 2. BROWNFIELD APPLICATION REQUIREMENTS Chapter 3. BROWNFIELD AGREEMENT REQUIREMENTS AND PROCEDURES Chapter 4. PUBLIC NOTICE REQUIREMENTS Chapter 5. DECISION ON BROWNFIELD AGREEMENT Chapter 6. MODIFICATION OF BROWNFIELD AGREEMENT Chapter 7. LIABILITY PROTECTION AND NO FURTHER ACTION LETTER Chapter 8. CANCELLATION OF NOTICE OF BROWNFIELD AGREEMENT Chapter 9. FEES AND TRUST FUND Chapter 10. HEARINGS AND ENFORCEMENT SUBPART I. GENERAL REQUIREMENTS

Chapter 1. GENERAL

Section 101. Purpose


The purpose of these regulations is to promote the voluntary remediation of contaminated sites in Mississippi. The regulations establish remediation requirements that are based on public health and environmental risks specific to the Brownfield Agreement Site. The formats and procedures set forth in these regulations are designed to advise a person, prior to submitting an application, of the information necessary to achieve the adequate and cost-effective characterization and remediation of a Brownfield Agreement Site. All information requirements may not be applicable for all Brownfield Agreement Sites as long as the Applicant provides written justification.

Section 102. Authority


The Mississippi Department of Environmental Quality (MDEQ) and the Mississippi Commission on Environmental Quality (MCEQ) are authorized to administer the requirements of the Act and the regulations promulgated there under as set forth in Mississippi Code Annotated Section 49-35-1 through 27.

Section 103. Definitions


As used in these regulations, the following terms have the specified meaning, except where otherwise indicated.

Absorption factors mean the chemical-specific values that represent the fraction of the chemical from an environmental medium such as soil that can pass across the exchange boundaries of the organism (e.g., skin, lungs, gut) for absorption. The relevant absorption factors for chemicals into humans will be those published by EPA (e.g., the EPA’s Dermal Exposure Assessment: Principles and Applications [EPA/600/8-91/011B), EPA Region 4's Supplemental Guidance to Risk Assessment Guidance to Superfund [RAGS]), those published in peer-reviewed literature, or other appropriate values as approved by MCEQ.

Act means the Mississippi Brownfields Voluntary Cleanup and Redevelopment Act, Miss. Code Ann. Sections 49-35-1 through 27.

AIHC means American Industrial Health Council.

Application means forms prescribed by MCEQ or MDEQ, the accompanying information specified in the forms, and other additional information requested by the MCEQ or the MDEQ pursuant to Section 49-35-7 of the Act.


Applicant or “Brownfield Applicant” means the person(s) who has applied to become a Brownfield Party.

Aqueous Solubility means the solubility of a pure substance in water. It is the maximum amount of a chemical that will dissolve in pure water at a temperature of 30 degrees Celsius.

Assessment endpoint means the explicit expressions of the actual environmental value that is to be protected. See also the definition for measurement endpoint.

ASTM means the American Society for Testing and Materials.

Background chemical means a substance which is: (a) consistently present in the environment at and in the vicinity of the Brownfield Agreement Site; and (b) attributable to geologic or natural conditions.

Bioconcentration means the uptake and accumulation or concentration of a chemical in an individual organism.

Biomagnification means the accumulation of a chemical (that has the property to bioconcentrate) in humans or an animal through the food chain, i.e., from the ingestion of organisms or other animals tainted with the chemical.

Brownfield Agreement or “Agreement” means an agreement between the Applicant and MCEQ for the remediation of a Brownfield Agreement Site.

Brownfield Agreement Order or “Agreement Order” means an Order issued by the Commission which embodies a Brownfield Agreement.

Brownfield Agreement Site or “site” means Brownfield Property that is remediated under a Brownfield Agreement. The Site shall consist of the Brownfield Property that is the subject of the application and any other Brownfield Property:


Brownfield Party means any person who desires to execute and implement a Brownfield Agreement.

Brownfield Property means any property where use is limited by actual or potential environmental contamination, or the perception of environmental contamination, and that is or may be subject to remediation under any state environmental law, regulation or program or under the Comprehensive Environmental Response, Compensation and Liability Act of 1980, as amended, 42 USCS 9601 et seq. (1997)(CERCLA), but does not include any of the following:

Brownfields Corrective Action Plan (CAP) means a document or a set of documents that outlines remedial objectives, scope of the design investigation, conceptual designs, pre-construction design specifications, construction management and schedules, quality control, and operation and maintenance in connection with remedial actions conducted pursuant to the Act and these regulations. The content and format of the CAP is provided in MDEQ’s “Brownfields Corrective Action Plan Format,” which may be required as part of the application.

Brownfields Corrective Action Report means a document or a set of documents that provide information supporting the remediation of human health and environmental risks specific to the Brownfield Agreement Site to levels appropriate for the land-use of the Site.

Brownfields Site Characterization Report means a document or a set of documents that provides information supporting the delineation of the vertical and horizontal extent of contamination on or under a Site in order to develop remediation requirements for the Site or to determine that remediation is necessary. The contents and format of the Brownfield Site Characterization Report is provided in MDEQ’s “Brownfields Site Characterization Report Format,” which shall be required as part of the application.

Carcinogen means any substance which may cause cancer as identified by the U.S. Environmental Protection Agency (EPA).

Carcinogenic risk or upperbound excess lifetime carcinogenic risk means the likelihood of developing cancer or tumor incidence for an individual from lifetime exposure to a carcinogen, not including exposure to cancer causing background chemicals.

CERCLA means the Comprehensive Environmental Response, Compensation, and Liability Act of 1980 (Superfund) (Public Law 96-510), as amended by the Superfund Amendments and Reauthorization Act of 1986, 42 U.S.C. 9601 et seq.

Chemical of Concern (CoC) means a contaminant or a chemical that poses public health and environmental risks specific to the Brownfield Agreement Site.

Complete Application means a Brownfield Agreement Application which the MDEQ determines contains information addressing each application requirement of the Act and these regulations and contains all information necessary to initiate formal processing of the application, as determined by MCEQ. Only a complete application constitutes an application for the purposes of Section 49-35-7(2).

Cost effective, when applied to remediation requirements, use restrictions, or engineering controls, means that these measures are economically and technically feasible and practicable in protecting human health or the environment for the intended use of a Brownfield Agreement Site.

Cumulative excess cancer risk means the upper bound on the estimated cancer risk above the background risk associated with exposure to multiple hazardous substances or multiple exposure pathways.

Cumulative site risk means the summation of risks to a human receptor or ecological receptor from one or more hazardous substances. The cumulative site risk for noncarcinogens is the site’s hazard index. The cumulative site risk for carcinogens is the cumulative excess cancer risk.

DAF means a Dilution-Attenuation Factor approved for use in the Brownfields Program by MDEQ.

Deterministic risk assessment means the traditional approach to estimating a site’s potential risk by solving the risk algorithm (intake multiplied by the dose-response) analytically by the assignment of average or high-end values in the algorithm to calculate the risk (dependent variable) posed by independent variables (such as exposure factors and exposure point concentrations that produce the intake).

DNAPL means dense non-aqueous phase liquid.

Ecological receptor of concern means specific ecological communities, populations, or individual organisms protected by federal or state laws and/or regulations, or those local populations which provide important natural or economic resources, functions and values.

Ecosystem means an integrated, self-functioning system consisting of interactions among both the biotic community and abiotic environment within a specified location in space and time.

Effective Solubility means the solubility of a compound that will dissolve from a chemical mixture (e.g., gasoline). The effective solubility of a compound from a chemical mixture is less than its aqueous solubility.

Engineering control means an existing condition or modification to a Brownfield Agreement Site that reduces or eliminates the potential for exposure to contaminants. These conditions or modifications may include, but are not limited to, physical or hydraulic control measures (such as groundwater recovery trenches and leachate collection systems), groundwater treatment systems, engineered caps, liner systems, slurry walls, or permanent structures, but shall not include the exclusive use of security fencing.

Environmental contamination means the presence of hazardous substances or constituents that pose unacceptable risks to the environment, humans, or ecological receptors.

EPA means the United States Environmental Protection Agency.

Executive Director means the Executive Director of the Mississippi Department of Environmental Quality.

Exposure means contact of an organism with a chemical or physical agent. Exposure is quantified by exposure point concentration in an exposure medium (such as soil, sediment, air, groundwater, and surface water) and the intake of the medium (expressed as the amount of the medium taken into the body by the organism per unit body weight per day).

Exposure factors means values used to estimate exposure in risk assessment, such as the number of days per year, number of years that exposure is expected to occur, the amount of contaminated media that a person or an organism might contact per day, the extent of uptake or absorption of the medium contacted, and the body weight.

Exposure pathway means the manner by which a person or an organism may be exposed to a chemical of concern or contaminant. A complete exposure pathway consists of a source, a release from a source, a migration and transport mechanism, an exposure medium (e.g., air) or media (in cases of intermediate transfer), an exposure point, and an exposure route.

Exposure point concentration (EPC) is the amount of CoC available at the exchange boundaries of the organism (e.g., skin, lungs, gut) for absorption by humans.

Exposure route means the portal of entry which results in the intake of a contaminated medium into the human body or an organism (e.g., ingestion, dermal contact, and inhalation).

Fate and Transport means the behavior and movement of a chemical through an environmental media. The movement is affected by many factors such as sunlight (UV radiation), wind-blown or wave actions, microbial activity, groundwater and surface water flow, chemical properties (e.g., solubility, density), physical-chemical properties of the medium (e.g., grain size, porosity, permeability, and organic carbon content), and presence of solubility-enhancing solvents or buried piping and utilities.

Free product means a discharged hazardous substance or environmental pollutant that is present in the environment as a floating or sinking non-aqueous phase liquid. Free Product is considered present if:

Groundwater quality standard means the chemical-specific numerical value published by EPA as Maximum Contaminant Level (MCL). Where the groundwater intersects surface water, ambient water quality criteria values identified in the “Mississippi Water Quality Criteria for Intrastate, Interstate, and Coastal Waters” or other values determined by the MDEQ to be protective will be applicable.

Habitat means the area or type of environment to which an organism or biological population is indigenous.

Hazard index means the sum of the hazard quotients for multiple substances and/or multiple exposure pathways.

Hazard quotient means the value which quantifies non-carcinogenic hazard for a single chemical for an individual receptor over a specified exposure period. The hazard quotient is equal to the ratio of an intake of a chemical to the chemical’s reference dose. Hazard quotient shall be based on similar-acting non-carcinogens, i.e., systemic toxicants that act on the same organ or organ system.

Hazardous substance mean any substance which is a hazardous substance as defined in Section 101(14) of the Comprehensive Environmental Response, Compensation, and Liability Act of 1980, and any substance which is designated as a hazardous substance under Section 102 of such Act.

Integrated Risk Information System (IRIS) means the database system of that name developed and maintained by EPA.

Land-use restriction or institutional control means the limitation on use of or access to a Brownfield Agreement Site to reduce or eliminate the potential for exposure to contaminants. These restrictions may include, but are not limited to, deed restrictions, use restrictions, restrictive covenants, or restrictive zoning.

Legal and Equitable Interest Owners mean persons who have a legal or equitable interest in the Brownfield Agreement Site and may include, but are not limited to, property owners, tenants, or lending institutions.

LNAPL means light non-aqueous phase liquid.

Local government means a county or municipality within the State of Mississippi.

MCL means maximum contaminant level published by EPA under the Safe Drinking Water Act (42 United States Code 300f et seq.).


MCEQ means the Mississippi Commission on Environmental Quality.

MDEQ means the Mississippi Department of Environmental Quality.

Measurement endpoint means the measurable responses to chemicals or physical changes in the environment that are related to the valued characteristics chosen as the assessment endpoint.

mg/Kg means milligram per kilogram.

mg/L means milligram per Liter.

Monitored Natural Attenuation means remediation by natural attenuation that is monitored to determine achievement of remediation goals over a specified time period.

Natural Attenuation means the reduction in the concentration or mass of a substance and its breakdown products in an environmental medium (such as groundwater), due to naturally occurring physical, chemical, and biological processes without human intervention or enhancement. These processes include, but are not limited to, dispersion, diffusion, sorption and retardation, and degradation processes such as biodegradation, abiotic degradation and radioactive decay.

NAPL means non-aqueous phase liquid, which can be heavier or lighter than water. NAPL that is lighter than water is called light non-aqueous phase liquid (LNAPL) or a floater. NAPL that is heavier than water is called dense non-aqueous phase liquid (DNAPL) or a sinker.

NPL means the National Priorities List published by EPA pursuant to CERCLA Section 105.

Person means any person as defined in Section 17-17-3 of the Mississippi Code Annotated.

Potentially responsible party means a person who is or may be liable for remediation under any state or federal law, regulation, or program.

Previously unknown contaminant means any chemical or contaminant that has not been delineated in the Brownfields Site Characterization Report and/or remediated to a risk-level appropriate for the land-use of the Site as described in the Brownfields Corrective Action Report.

PRG means the Preliminary Remediation Goal developed by EPA Region 9 for a specific chemical.

Principal threat chemical means a CoC, by itself or with other CoCs, which has been shown to contribute a substantial part (majority) of the total Site risk based on a Tier 3 site-specific risk assessment.

Probabilistic risk assessment means a site-specific risk assessment performed using a statistical sampling technique that produces a probabilistic approximation of the potential risk from the site-specific risk assessment algorithm or model.

Property boundary or site boundary means the boundary of the Brownfield Agreement Site.

Quality Assurance Project Plan (QAPP) means a document or set of documents that integrates all technical and quality aspects of a project, including planning, implementation, and assessment. The purpose of the QAPP is to document planning results for environmental data operations and to provide a project-specific “blueprint” for obtaining the type and quality of environmental data needed for a specific decision or use.

Quality Management Plan (QMP) means a document or set of documents that describes how an organization structures its quality system and describes its quality policies and procedures, criteria for and areas of application, and roles, responsibilities, and authorities. It also describes an organization’s policies and procedures for implementing and assessing the effectiveness of the quality system.

Quantitation limit means the lowest concentration for an analytical test method and sample matrix at which the quantity of a particular substance can be routinely measured with a stated degree of confidence. The quantitation limit for a particular sample analysis and analytical method is called the sample quantitation limit (SQL) or reporting limit.

Radioactive material means a radionuclide or substance that spontaneously emits ionizing radiation or particles.

RBC means the risk-based concentration developed by utilizing equations developed by EPA Region III for a specific chemical.

RBSL means risk-based screening levels developed by ASTM in the Emergency Standard Guide (ES 38-94) and in the Standard Guide for Risk-Based Corrective Action Applied at Petroleum Release Sites (ASTM E 1739-95), 1995.

RCRA means the Resource Conservation and Recovery Act of 1976, 42 USC 6901 et seq.

Readily apparent harm means the observations of stressed biota and/or their habitat.

Receptor means environmental resources, including but not limited to, plant and animal species, humans, sensitive environments and habitats, water supply wells, and locations that have the potential to be, or have actually been, exposed to contamination.

Reference concentration (RfC) means a value representing a daily exposure level for the human population, including sensitive subpopulations, that is not likely to cause deleterious and non-reversible adverse noncancer health effects during a chronic or subchronic exposure period. Reference concentration is generally expressed in the unit of milligram per cubic meter (mg/m3).

Reference dose (RfD) means a value representing a daily exposure level for the human population, including sensitive subpopulations, that is not likely to cause deleterious and non-reversible adverse noncancer health effects during a chronic or subchronic exposure period. Reference dose is generally expressed in the unit of milligram per kilogram body weight (mg/Kg/day).

Regionally Prevalent Chemical means a substance found throughout a substantial geographic region, as approved by MDEQ (e.g., Delta region), that can be attributed to conditions, as approved by MDEQ, such as atmospheric deposition and aerial application.

Remediation means action to cleanup, mitigate, correct, abate, minimize, eliminate, control, treat, remove, or to implement institutional and/or engineering controls in order to prevent the spreading, migration, leaking, leaching, volatilization, spilling, transport, exposure, or further release of a contaminant to the environment in order to protect public health or the environment.

Remediation goal (RG) means the target cleanup level or objective that is cost-effective, implementable, and protective of human health and the environment. The RG can be quantitative, i.e., numerical cleanup level (generally expressed in mg/kg [soil or sediment] or mg/L [water]) or can be qualitative (e.g., basis for an engineered barrier, to prevent/minimize exposure). Fencing alone cannot be the RG.

Restricted site means a Brownfield Agreement Site where access to the general public is limited and/or controlled. The restrictions may include, but are not limited to, deed restrictions, use restrictions, restrictive covenants, or restrictive zoning.

Risk means the likelihood or probability that a hazardous substance, when released to the environment, will cause adverse effects in exposed humans or other biological receptors. Risk is further classified as carcinogenic (from exposure to carcinogens) or noncarcinogenic (from exposure to noncarcinogens, i.e., systemic toxicants).

Risk assessment or “site-specific risk assessment” means a site-specific characterization of the current or potential threats that may be posed to human health and the environment by contamination migrating to or in groundwater or surface water, discharging to the air, leaching through or remaining in soil, bioaccumulating in the food chain, or other complete and significant exposure pathways identified in the Site Conceptual Exposure Model (SCEM). Key components of a risk assessment are the identification of hazard (i.e., identifying site-related chemicals and their concentrations in the exposure media), exposure assessment (identifying complete and significant exposure pathways and quantifying intake), toxicity assessment (identifying the toxic effects and dose-response [toxicity value]), risk characterization, and discussion of uncertainties. For the purposes of these regulations, a Tier 3 Risk Assessment is considered a “site-specific risk assessment.”

Risk-based remediation requirement means remediation a requirement based on public health and environmental risks specific to a Brownfield Agreement Site.

Risk Management means the evaluation of options or measures to reduce risk, including, but not limited to, such options as no further action, monitoring only, or gathering additional data before making a decision.

Sediment means particles in surface waters or wetlands or on the bottom of surface waters or wetlands that are derived from the erosion of rock, minerals, soils and biological materials, as well as chemical precipitation from the water column. Sediment particles are transported by, suspended in or deposited by water.

Sensitive environment means an area of exceptional environmental value, where a discharge or release could pose a greater threat than a discharge to other areas, including but not limited to: wetlands; habitat used by state or federally designated endangered or threatened species; national or state fish and wildlife refuges and fish and wildlife management areas; and state and federal designated wild and scenic rivers.

Site Conceptual Exposure Model (SCEM) means a graphical presentation of actual or hypothetical conditions, based on current data and understanding of the Site, under which the chemicals of concern or contaminants from a Brownfield Agreement Site may be released from a source, moved (migration/transport) in the environment, present in the exposure media, and absorbed by the receptor through the exposure routes. The SCEM will be used to identify data needs to assess risk and may be modified to consider new data in determining whether an exposure pathway is incomplete or complete. The SCEM is used in the development of remediation goals and identification of remedial options.

Slope factor means the upperbound estimate of probability in the occurrence of excess cancer risk (increase in cancer risk over the background risk) associated with a specific carcinogen for an individual who is exposed to a unit of intake over lifetime. The unit for a slope factor is the probability per unit intake, i.e., the inverse of milligram per kilogram body weight (mg/Kg/day)-1.

SPLP means Synthetic Precipitation Leaching Procedure, an EPA analytical method (Method 1312) published in SW-846.

SSL means a soil screening level developed by EPA in the Soil Screening Guidance: Technical Background Document (EPA/540/R-95/128).

Stakeholders mean persons or parties who have a legitimate interest in the remediation and redevelopment of the Brownfield Agreement Site. These persons include, but are not limited to, the property owners adjoining the Brownfield Agreement Site property and local governments.

SW-846 means Test Methods for Evaluating Solid Waste - Physical/Chemical Methods published by the U.S. Environmental Protection Agency, Office of Solid Waste on November 1986, and its updates.

Systemic Toxicant means a substance or agent that may enter the body, injure an organ or organ system, or have an effect other than causing cancer. The toxicity value used for risk characterization of the chronic effect for a systemic toxicant is the reference dose (RfD).

Target remediation goals (TRGs) mean risk-based media concentrations utilized in the Tier 1 evaluation of human health and environmental impacts in these regulations. Soil TRGs are soil concentrations developed by MDEQ for individual chemicals to address the soil ingestion and inhalation exposure pathways and environmental risks. Groundwater TRGs are either the groundwater quality standards (current MCLs published by EPA) or risk-based remediation goals derived by MDEQ. Soil and groundwater TRGs are provided in MDEQ’s Risk Evaluation Procedures developed for these regulations. Surface water TRGs are the water quality criteria published by the MDEQ. TRGs are to be compared with the exposure point concentrations. TRGs alone do not always trigger the need for response actions or define unacceptable levels of contaminants in soil or groundwater. The Tier 1 TRGs may either be used as “default” remediation goals or as screening values that will initiate a Tier 2 Evaluation or Tier 3 Evaluation.

Target risk means a de minimis or insignificant risk to humans below which further action (remediation, institutional control, monitoring, etc.) is not warranted.

Technical Impracticability or “Technically impracticable” means the inability to achieve certain remediation requirements and is based on engineering feasibility and reliability, cost-effectiveness, and risk-based considerations. For the purposes of these regulations, EPA’s OSWER Directive 9234.2-25: “Guidance for Evaluating the Technical Impracticability of Groundwater Restoration,” dated September 1993 may be utilized in developing a demonstration of technical impracticability with regard to groundwater and soil remediation, free product removal, and other site-specific conditions approved by MDEQ.

Tier 1 Evaluation means a comparison of CoC exposure point concentrations in soil or sediment with chemical-specific TRGs for the evaluation of human health and environmental impacts and an evaluation of ecological impacts through completion of an Ecological Checklist. Ecological evaluations are used to determine whether ecological receptors of concern are present and may include, but are not limited to, the collection of field observation data for any readily apparent harm on the ecological receptors of concern.

Tier 2 Evaluation means a more in-depth evaluation of site-specific conditions beyond the Tier 1 Evaluation methodology. The Tier 2 Evaluation may include, but is not limited to, an evaluation of site-specific conditions by:

Tier 3 Evaluation means a site-specific risk assessment (Risk Assessment). The Tier 3 human health risk evaluation is the characterization of the risks of cancer and adverse non-cancer health effects in humans in accordance with EPA’s Risk Assessment Guidance for Superfund (RAGS) and other risk assessment guidance published by EPA including, but not limited to, the Adult Lead Model and the Integrated Exposure Uptake Biokinetic Model (IEUBK) for lead. The Tier 3 ecological risk evaluation is the characterization of environmental effects qualitatively or quantitatively in accordance with the EPA’s Framework for Ecological Risk Assessment guidance, as amended.

Treatability study means the testing and documentation activities to evaluate the effectiveness of a proposed remediation method (remedial action) prior to full scale design and implementation. Treatability study includes, but is not limited to, bench scale studies and pilot scale studies, and may be required by the Corrective Action Plan if the remediation method has not been evaluated by EPA or an independent consultant or trade association to be capable of treating the medium (or medium of similar physical and chemical characteristics) at the Brownfield Agreement Site.

Unacceptable risks mean that the carcinogenic risks, non-carcinogenic hazards, or ecological risks posed by the CoCs at the point of exposure, according to a Tier 1, Tier 2, or Tier 3 Evaluation, have exceeded established target risk levels for humans or ecological receptors. The term can also be applied qualitatively if there is a sufficient basis to conclude that the likelihood of impact to the ecological receptors of concern or the sensitive environment is high based on findings of an ecological risk assessment.

Unrestricted site, relevant to a Brownfield Agreement Site, means that the use of the property is not restricted by an applicable Brownfield Agreement.

Volatile Compounds means those compounds with a Henry’s Law Constant greater than 1 x 10-5 and a molecular weight less than 200 g/mole, for all media.

Wetlands means those areas where water is at, near or above the land surface long enough to be capable of supporting aquatic or hydrophytic vegetation, and which have soils indicative of wet (hydrid) conditions.

Section 104. Acronyms


CAP Corrective Action Plan
CERCLA Comprehensive Environmental Response, Compensation, and Liability Act of 1980 (Superfund) (Public Law 96-510), as amended by the Superfund Amendments and Reauthorization Act of 1986
CoC Chemical of Concern
EPA United States Environmental Protection Agency
MCEQ Mississippi Commission on Environmental Quality
MCL Maximum Contaminant Level
MDEQ Mississippi Department of Environmental Quality
NPL EPA’s National Priorities List
OSWER EPA’s Office of Solid Waste and Emergency Response
QAPP Quality Assurance Project Plan
QMP Quality Management Plan
QA/QC Quality Assurance/Quality Control
RBCs Risk-Based Concentrations
RCRA Resource Conservation and Recovery Act of 1976, as amended, 42 USC 6901 et seq.
RG Remediation Goal
SCEM Site Conceptual Exposure Model
TPH Total Petroleum Hydrocarbon
TRGs Target Remediation Goals
VEP Mississippi Uncontrolled Site Voluntary Evaluation Program
UCL Upper Confidence Level

Section 105. Applicability


a) The following sites are not eligible for inclusion in a Brownfield Agreement Site:


b) The MCEQ may exclude properties that pose an imminent and substantial threat to human health and the environment and require immediate remedial and/or cleanup action.

c) The MCEQ may exclude properties that are under an existing MCEQ agreement or order.

d) Sites that are participating in the Uncontrolled Site Voluntary Evaluation Program (VEP) pursuant to Mississippi Code Annotated Section 17-17-54 prior to the effective date of these regulations shall not be required to pay the initial $2000.00 application fee under these regulations if the Applicant is current on any payments due MDEQ under the VEP.

e) In order to be eligible for the Brownfield Program, an Applicant must satisfy the requirements regarding financial resources, technical resources, managerial resources, and compliance history set forth in these regulations.

f) Only Brownfield Properties which require remediation may be included in a Brownfield Agreement.

g) The Brownfield Party shall comply with all applicable federal and state laws and regulations.

h) Nothing in the Brownfield Agreement or these regulations shall be construed to convey or determine any interest in property.

i) Nothing in the Brownfield Agreement or these regulations shall be construed to be an allocation of costs or an indemnification by the State, MDEQ, and/or MCEQ.


Chapter 2. BROWNFIELD APPLICATION REQUIREMENTS

Section 201. General Requirements


a) Brownfield Agreement applications must be filed in the format prescribed by MDEQ. Prior to approval, the application must be complete and must contain all of the information required by MDEQ, including, but not limited to, information necessary to demonstrate the following:


b) If the Brownfield Applicant has demonstrated to the satisfaction of MDEQ that activities on or under the Brownfield Agreement Site involving the use, extraction, or production of mineral interests will not increase the level of risk to the public health or the environment beyond the level that forms the basis for the risk-based remediation requirements in the Brownfield Agreement, then the current owners and lessees of those mineral interests (including legal and equitable) in or under the Brownfield Properties that are the subject of the application are not required to give written approval for the submission of the application and the inclusion of their property interest in the Brownfield Agreement Site. All owners and lessees of a legal or equitable interest in the surface and/or mineral estates of the Brownfield Properties that are the subject of the application who do not give written approval for execution of the Brownfield Agreement shall be subject to Section 701(e)(3) of these regulations. Otherwise, written approval of the mineral interest owner(s) for inclusion of the Brownfield Property in the Brownfield Agreement site must be provided on the form prescribed by MDEQ;

c) As part of the application, the Applicant shall submit a title certificate prepared by an attorney who is licensed to practice law in the State of Mississippi identifying the following:

d) As part of the application, the Applicant shall submit a copy of any local zoning requirements, classifications, statutes or ordinances, comprehensive zoning plan designations, and/or any current land use approvals obtained regarding the Brownfield Property and the property contiguous to the Brownfield Property.

e) At the time a Brownfield Agreement application is filed, the Applicant shall submit $2000.00 in the form of a check or money order made payable to MDEQ as advance costs for the costs described in paragraph (f).

f) At the time a Brownfield Agreement application is filed, the Applicant must execute a statement in the form required by MDEQ that provides that the Applicant agrees to pay all direct and indirect costs of MDEQ associated with the processing of the Brownfield Agreement application and administration of the Brownfield Agreement.

g) As part of the application, the Applicant shall submit a schedule which sets forth its estimate of the amount of time it expects will be required to complete the Brownfield Agreement.

h) With regard to financial resources, the applicant shall be required to file with MDEQ, as part of its application, an estimate of the costs of performance of all requirements of the Brownfield Agreement including corrective action, operation and maintenance, monitoring, post-closure activities, and contingency actions. The cost estimate shall be based on a professional third party’s cost of performing all of the requirements of the Brownfield Agreement. These cost estimates must be submitted to MDEQ for its concurrence. The applicant shall provide MDEQ proof of financial resources in an amount equal to the cost estimates for performance of all requirements of the Brownfield Agreement including corrective action, operation and maintenance, monitoring, closure, post-closure activities, and contingency actions. Proof of financial resources, if applicable, may include the following financial instruments: insurance, escrow accounts; surety bonds, including performance or financial guarantee bonds; irrevocable letters of credit; certificates of deposit; securities; and/or other documents approved by MDEQ. The financial instruments shall be issued by a surety company or financial institution licensed to do business in the State of Mississippi. MDEQ may, in its discretion, exempt an applicant from these financial resource requirements based on the applicant’s demonstration of financial resources submitted to MDEQ in another MDEQ program and/or such other factors deems appropriate. In the event the cost estimates to complete all requirements in the Brownfield Agreement increase or decrease, MDEQ may require the Brownfield Party to submit additional and/or amended financial instruments.

i) With regard to technical resources, the applicant shall be required to file with the MDEQ, as part of the application on a form prescribed by the MDEQ, a statement certifying that the Applicant shall utilize a consulting firm listed on the approved list of Brownfield Consulting Firms or the staff of the MDEQ.

j) With regard to managerial resources, the applicant shall be required to file with MDEQ, as part of its application on a form prescribed by MDEQ, a statement of key personnel considered essential to the work being performed under the Brownfield Agreement. Prior to removing, replacing, or diverting any of the specified individuals, the Brownfield Party shall notify MDEQ in advance and shall submit justification, including proposed substitutions, in sufficient detail to demonstrate that the substitutions have sufficient qualifications to manage all assignments associated with the Brownfield Agreement Site.

k) With regard to compliance history, the MDEQ may require the applicant to submit the following:

l) The applicant shall submit all other information required by MDEQ.

Section 202. Procedural Requirements


a) Within thirty (30) days after the date an application is submitted to MDEQ, MDEQ shall review the application to determine whether the application is a complete application and forward a letter to the Applicant advising either (1) that the application is complete or (2) that the application is incomplete and listing the specific sections that must be submitted or supplemented to make the application complete.

b) Within thirty (30) days after the date that MDEQ forwards a letter to the Applicant advising that the application is complete, MCEQ shall issue an order which sets forth a schedule for:

c) The Applicant shall promptly update and/or correct information previously submitted as part of the application whenever the Applicant discovers that this information is incomplete or inaccurate.

d) If Brownfield Property other than that property which is the subject of the original application is identified as necessary for inclusion in the Brownfield Agreement Site, the Brownfield Party shall obtain written approval, on the form prescribed by the MDEQ, from all persons who have an interest in the additional Brownfield Property for inclusion of that Brownfield Property in the Brownfield Agreement Site, in accordance with Section 201(a)(3) and (b) of these regulations.

e) If MDEQ’s technical review indicates that no remediation is required at the Site, MDEQ will issue a letter so stating.

Section 203. Brownfield Consulting Firm Requirements


a) In order to be listed on the approved list of Brownfield Consulting Firms, a firm must, at a minimum,


b) An approved Brownfield Consulting Firm must notify MDEQ within 10 days of any modification in the information previously submitted, and must submit updated information within 30 days of the modification. If the modification renders the firm unable to remain on the list of approved Brownfield Consulting Firms, then MCEQ may remove the firm from that list. MDEQ or MCEQ may require the Brownfield Party to certify its retention of an approved Brownfield Consulting Firm within 30 days of a determination that the Party’s consultant no longer is an approved Brownfield Consulting Firm.

c) All key personnel of an approved Brownfield Consulting Firm must attend MDEQ-approved continuing education, as required by MDEQ.

d) An approved Brownfield Consulting Firm may be removed from the approved list for a period of time specified by the MCEQ for any of the following:

e) Any interested party may request a hearing before MCEQ as provided in Sections 49-17-31, 49-17-33, 49-17-35, 49-17-37, 49-17-41 or other applicable provisions of law regarding any of the provisions of this section, including but not limited to:

f) The listing of a Brownfield Consulting Firm does not authorize any individual to perform work from which it is restricted by any state or federal law or regulation.

g) MDEQ may, itself, conduct those activities necessary to delineate or remediate Brownfield Property.

Chapter 3. BROWNFIELD AGREEMENT REQUIREMENTS AND PROCEDURES

Section 301. General Requirements


a) Once MDEQ has completed its review of the application and any other information required to be submitted by the Applicant, MDEQ shall prepare a proposed Brownfield Agreement.

b) The Brownfield Agreement shall contain the following:


c) Prior to approval of the Brownfield Agreement by the Commission, the Brownfield Party shall submit to MDEQ, on a form prescribed by MDEQ, a statement of consent signed by all owner(s) of interests in the Brownfield Property (other than the Brownfield Party) stating that such owners have read and understand the Brownfield Agreement and that they consent to the inclusion of their property interest in the Brownfield Agreement Site.

d) Prior to execution of the Brownfield Agreement, and with thirty days written prior notice to MDEQ, the applicant may withdraw the Brownfield Agreement application. The applicant shall be required to pay all costs associated with the processing of the Brownfield Agreement application prior to the effective date of withdrawal. Failure to pay all accrued costs shall subject the Brownfield Party to remedies contained in Mississippi Code Annotated Section 49-17-43. In addition, MCEQ may proceed with any and all remedies available to it with regard to the Brownfield Property and/or Brownfield Applicant.

Section 302. Risk-based Remediation Requirements and Land-use Restrictions


a) A Brownfield Agreement shall establish remediation requirements that are based on public health and environmental risks specific to the Brownfield Agreement Site and in accordance with Mississippi Code Annotated Section 49-35-7. In establishing the risk-based remediation requirements in a Brownfield Agreement, MCEQ shall consider the use of appropriate land-use restrictions and/or engineering controls proposed by the Brownfield Party. MCEQ may determine that permanent engineering controls in conjunction with appropriate land-use restrictions satisfy the remediation required by MCEQ in the Brownfield Agreement. These risk-based remediation requirements may include contaminant-specific, state-specific, site-specific and/or likelihood-of-risk methodologies for the implementation of these risk-based remediation requirements. Any party to a Brownfield Agreement who complies with the requirements of a Brownfield Agreement may rely on these risk-based remediation requirements, land-use restrictions and engineering controls as governing the extent of remediation required to be performed by the Brownfield Party on or under the Brownfield Agreement Site for all purposes of the Act. Any risk-based remediation requirements, land-use restrictions and engineering controls implemented under a Brownfield Agreement shall be conducted in a cost-effective manner, consistent with projected future uses of the Brownfield Agreement Site.

b) Remediation options include, but are not limited to, the use of appropriate land-use restrictions, engineering controls, monitored on-site containment, excavation, monitored natural attenuation, soil vapor extraction, dual-phase extraction, pump & treat, phytoremediation, landfarming, and/or any other remediation option or combinations thereof approved by MCEQ.

c) The three procedures for determining risk-based remediation requirements follow:


d) Risk-based remediation goal - The risk-based remediation goal (RG) may be qualitative or quantitative. A qualitative RG involves the exclusion of exposure pathways by engineering controls. A quantitative RG involves calculating the maximum numerical CoC(s) concentration in a medium which would not exceed the acceptable baseline risk at the exposure point. The numerical risk-based RG may be adjusted upward or downward depending on risk management considerations as approved by the MDEQ.

e) Free Product - Free Product refers to the presence of a hazardous substance or an environmental pollutant in the environment as a floating or sinking non-aqueous phase liquid. Free Product is considered present if measurable using best available technologies or if the concentration of the chemicals of concern in groundwater or soils is at or above the solubility limit for all chemicals or soil saturation limit for all chemicals with a melting point less than 30 degrees Celsius. On a site-specific basis, MDEQ may require either the effective solubility or the aqueous solubility to be utilized. Free product must be removed from the Brownfield Agreement Site, unless it can be demonstrated to the satisfaction of MDEQ that removal of the free product is (1) technically impracticable and that (2) the contamination is confined and will remain confined within the site boundaries.

f) Historical data - Historical data approved by MDEQ may be submitted in lieu of collecting new data provided the Site characterization data requirements are summarized and presented in accordance with the Site Characterization Work Plan and Report Formats and the data was collected in a manner consistent with appropriate sampling protocols. All detailed information must be referenced in the reports including sampling protocols. In any event, relevant historical Site characterization reports shall be submitted with the application.

g) Site Conceptual Exposure Model (SCEM) - The Brownfields Applicant must complete a BASELINE SCEM and a REMEDIAL SCEM on the forms prescribed by MDEQ as described in MDEQ’s Risk Evaluation Procedures.

h) Petroleum Hydrocarbons - Brownfield Agreement Sites impacted with petroleum compounds must assess the area(s) and media of impact for petroleum hydrocarbon compounds (e.g., benzene, toluene, ethylbenzene, total xylenes, and polynuclear aromatic hydrocarbons). In areas where the concentration of these constituents cannot be determined due to dilution, and/or interference, the Brownfield Applicant may either (1) use the petroleum hydrocarbon methodologies as established in MDEQ’s Risk Evaluation Procedures or (2) another TPH risk evaluation methodology approved by MDEQ.

i) Land-Use Restrictions - Before conducting the risk-based evaluation and/or corrective action, if applicable, land-use for the Brownfield Agreement Site shall be proposed by the Applicant, in consultation with MDEQ, as either restricted or unrestricted.

Chapter 4. PUBLIC NOTICE REQUIREMENTS

Section 401. Public Notice Requirements


a) Public Notice by the MCEQ:


b) Public Notice by the Applicant

c) Notice of Brownfield Agreement Site

d) Public Hearing Regarding Brownfields Agreement

e) MDEQ shall provide to MCEQ for review before its consideration of the proposed Brownfield Agreement all public comments and the transcript of any public hearing on the proposed Brownfield Agreement.

Chapter 5. DECISION ON BROWNFIELD AGREEMENT

Section 501. Decision on Brownfield Agreement


a) The approval of a Brownfield Agreement shall be based on a complete application which MDEQ determines to contain all information required under the Act or these regulations. If MCEQ finds that the proposed Brownfield Agreement complies with the Act and these regulations, the MCEQ, by order, shall approve the proposed Brownfield Agreement. After approval of the Brownfield Agreement, the Executive Director and the Brownfield Party shall execute the Brownfield Agreement.

b) MCEQ may consider an Applicant’s financial resources, technical resources, managerial resources and compliance history in determining whether or not to approve a Brownfield Agreement.

c) Prior to approval of the Brownfield Agreement, MCEQ may require the applicant to demonstrate to the satisfaction of MCEQ that contamination (the source of which is not environmental contamination or activities on or under the Brownfield Property that is the subject of the application but which is contributing or potentially contributing to contamination on or under the Brownfield Property that is the subject of the application) will not migrate onto the Brownfield Property or otherwise compromise the level of remediation of the Brownfield Property required by the Brownfield Agreement. This demonstration may include institutional controls, engineering controls or other preventive measures. In the event information is presented to MCEQ that migration of contamination has occurred or the level of remediation required under the Brownfield Agreement is being compromised, MCEQ may reopen the Brownfield Agreement.

d) MDEQ shall consider all environmental contamination on or under the Brownfield Property that is the subject of the application to be attributed to activities on or under said Property, unless the Brownfield Applicant can demonstrate to the satisfaction of MDEQ that (1) the source of environmental contamination is off-site and (2) that conditions on or under said Property have not and will not exacerbate or contribute to the contamination. MCEQ may, as it deems appropriate, inspect or require inspections; investigate or require investigations; evaluate or require evaluations; and/or issue orders regarding properties which are a source of contamination on or under the Brownfield Agreement Site.

e) MCEQ may enter into a Brownfield Agreement as proposed by MDEQ or may modify that agreement before entering into it. MCEQ subsequently may modify any Brownfield Agreement by entry of an order. The MCEQ orders issued under this Act shall be reviewable as provided in Section 49-17-41.

f) MCEQ may disapprove a proposed Brownfield Agreement or decline to enter into a Brownfield Agreement by entry of an order. In the order, MCEQ shall state the reasons for disapproval of the agreement or declining to enter into the agreement.

Section 502. Filing of Notice of Brownfield Agreement


Section 503. Notice by Brownfield Party of Conveyance of Brownfield Property


Until the Executive Director issues a "no further action" letter under Section 702 of these regulations, the Brownfield Party shall submit written notice to MCEQ at least thirty days prior to any sale, conveyance or other change in surface ownership of any portion of the Brownfield Agreement Site. Approval from MCEQ shall be required for any sale, conveyance or other change in surface ownership of any portion of the Brownfield Agreement Site owned by the Brownfield Party desiring to make the change in ownership, if the new surface owner will be required to or will assume an obligation to perform any obligations under the Brownfield Agreement. In that case, the Brownfield Party and the new surface owner jointly shall provide information satisfactory to MCEQ that the new surface owner has the financial, managerial and technical resources to complete performance of the Brownfield Agreement obligations to be transferred and that the new surface owner agrees to complete this performance. The new surface owner shall also submit a statement to MDEQ on a form prescribed by MDEQ which sets forth the requirements of the Brownfield Agreement for which it accepts responsibility. The Brownfield Party shall remain responsible for the payment of all reasonable direct and indirect costs of MDEQ associated with administration of the Brownfield Agreement until MDEQ receives a form from the new surface owner by which the new surface owner accepts responsibility for the payment of such costs. If MCEQ determines that the new surface owner has the necessary financial, managerial and technical resources, and an appropriate compliance history, to complete the performance of the Brownfield Agreement and that the new owner has agreed to do so, the MCEQ shall issue an order approving the transfer.

Section 504. Prospective Purchaser Notice


The Brownfield Party shall provide written notice of the Brownfield Agreement Site’s status as Brownfield Property to any prospective purchaser of any interest in the Brownfield Agreement Site.

Section 505. Executive Director Authority


Except for orders issued under subsections 501(b), 501(c), and 1002(c) of these regulations, MCEQ, under any conditions it may prescribe, may authorize the Executive Director to issue any orders required under this Act. A decision by the Executive Director shall be a decision of MCEQ and shall be reviewable as provided under Section 49-17-41.

Chapter 6. MODIFICATION OF BROWNFIELD AGREEMENT

Section 601. Conditions for Modifications


a) A Brownfields Agreement may be modified by order of MCEQ, if:


b) Minor modifications are not required to comply with the public notice requirements set forth in Section 401. All other modifications are required to go through public notice. Minor modifications include:
Chapter 7. LIABILITY PROTECTION AND NO FURTHER ACTION LETTER

Section 701. Liability Protection


a) Except as provided under Section 701(e) and Section 1002(c) of these regulations, a Brownfield Party who executes a Brownfield Agreement shall be relieved of liability to all persons other than the United States for:


b) The liability protection provided under and as limited by this section applies to the following persons to the same extent as to a Brownfield Party:

c) A person who conducts an environmental assessment on a Brownfield Agreement Site and who is not otherwise a potentially responsible party shall not become a potentially responsible party as a result of conducting the environmental assessment, unless that person increases the risk of harm to public health or the environment by failing to exercise due diligence and reasonable care in performing the environmental assessment.

d) The liability protection provided pursuant to this section shall become effective upon execution of a Brownfield Agreement by MCEQ and shall remain effective unless MCEQ removes the liability protection pursuant to Section 1002(c).

e) A Brownfield Party who satisfactorily completes the remediation required under a Brownfield Agreement, and any other person who receives liability protection under this section, shall not be required to perform additional remediation on or under the Brownfield Agreement Site unless:

Section 702. No Further Action Letter


Upon completion of the Brownfield Agreement, the Brownfield Party may petition MCEQ to determine that the Brownfield Party has completed performance of the Brownfield Agreement. If MCEQ determines after conducting an inspection of the Brownfield Agreement Site that the Brownfield Party has completed the Brownfield Agreement, MCEQ shall issue an order stating MCEQ’s conclusion. Following issuance of an order by MCEQ, the Executive Director shall issue a "no further action" letter. The letter shall include the following statement: "Based upon the information provided by [Brownfield Party] concerning property located at [location], it is the opinion of the Commission on Environmental Quality that [Brownfield Party] has successfully and satisfactorily implemented and completed the approved Brownfield Agreement. No further action is required to assure that the remediation required under the Brownfield Agreement is protective of public health and the environment in accordance with the existing and proposed uses of this property.”

Chapter 8. CANCELLATION OF NOTICE OF BROWNFIELD AGREEMENT

Section 801. Cancellation


If a Brownfield Party remediates a Brownfield Agreement Site to a risk level of unrestricted use, the Brownfield Party may petition MCEQ to cancel the Notice of Brownfield Agreement Site. If MCEQ issues an order canceling the notice, the current owner of the Brownfield Agreement Site shall file a statement issued by the Executive Director in accordance with MCEQ’s order canceling the notice in the office of the chancery clerk in any county in which the Brownfield Agreement Site is located. The Executive Director’s statement shall contain the names of the owners of the Brownfield Agreement Site as shown in the Notice of Brownfield Agreement Site and reference the book and page where the notice is recorded. After collecting the proper fee fixed in Section 25-7-9, the chancery clerk shall record the Executive Director’s statement as provided in subsection (e) of this section. The chancery clerk shall make a marginal entry on the Notice of Brownfield Agreement Site showing the date of cancellation and the book and page where the Executive Director’s statement is recorded, and the chancery clerk shall sign the entry.

Chapter 9. FEES AND TRUST FUND

Section 901. Fees


a) The Brownfield Party who submits a Brownfield Agreement application shall pay all reasonable direct and indirect costs of MDEQ associated with the processing of the Brownfield Agreement application and administration of the Brownfield Agreement less the advance costs required in Section 901(b) of this section, unless another funding source (e.g., EPA Cooperative Agreement) is available, acceptable, and approved by MDEQ.

b) A Brownfield Party who submits a Brownfield Agreement application for review by MDEQ shall pay advance costs of Two Thousand Dollars ($2,000.00) at the time the application is submitted to MDEQ. MDEQ will apply the Two Thousand Dollar ($2,000.00) advance costs to the final invoice as determined by MDEQ.

c) MCEQ shall set by order a schedule of costs for the processing of the Brownfield Agreement applications and the administration of Brownfield Agreements by MDEQ.

d) Reasonable direct and indirect costs shall include the cost of MDEQ’s utilization of the services of an independent contractor and/or contractual worker to evaluate information associated with the processing of the Brownfield Agreement application and administration of the Brownfield Agreement less the advance costs required in Section 901(b) of this section.

e) MCEQ may delegate to MDEQ responsibility for the collection of costs in Section 902(a)(1) and (2).

f) All costs under Section 902(a)(1) shall be due before a date specified by MDEQ, which shall be no less than thirty (30) days following the invoice date. If any part of the costs that are imposed is not paid within thirty (30) days after the due date, a penalty of up to twenty-five percent (25%) of the amount due may be imposed and added to that amount. Any penalty collected under this section shall be deposited into the Brownfields Cleanup and Redevelopment Trust Fund created by Miss. Code Ann. Section 49-35-25(4). If MDEQ pursues legal action to collect costs incurred, reasonable attorney's fees and costs may be assessed against the delinquent party pursuant to Miss. Code Ann. Section 49-35-25(7).

g) Any person required to pay costs under this section who disagrees with the calculation or applicability of the costs may petition MCEQ for a hearing in accordance with Section 49-17-35.

h) Costs collected under this section shall not supplant or reduce in any way the general fund appropriation to the MDEQ for the administration of this program, pursuant to Miss. Code Ann. Section 49-35-25(9).

i) MDEQ shall suspend any activities or actions related to the processing of the Brownfield Agreement application or administration of a Brownfield Agreement, if the Brownfield Party or Parties fails to pay any required costs or penalties imposed under this section. In addition, the MCEQ shall issue an order in accordance with Section 1002(b) requiring the Brownfield Party to pay the required costs within a certain time. Failure to comply with the order may subject the Brownfield Party to remedies set forth Mississippi Code Annotated Section 49-17-43 and removal of liability protection set forth in Section 701.

j) MDEQ shall submit a final invoice to the Brownfield Party within sixty (60) days of the issuance of a “No Further Action Letter” for Sites that do not require post-closure activities or compliance monitoring. For those Sites that require post-closure activities or compliance monitoring, MDEQ and the Brownfield Party shall agree upon reasonable direct and indirect costs associated with the administration of post-closure activities or compliance monitoring as outlined in the Brownfield Agreement.

k) Nothing in this section affects any existing program at MDEQ or affects any authority of MCEQ or MDEQ to take any action authorized by law.

Section 902. Brownfields Cleanup and Redevelopment Trust Fund


a) Pursuant to Miss. Code Ann. Section 49-35-25(4), there is created in the State Treasury a fund to be designated as the "Brownfields Cleanup and Redevelopment Trust Fund," referred to in this section as "fund," to be administered by the Executive Director.

b) Monies in the fund shall be utilized to pay reasonable direct and indirect costs associated with the processing of the Brownfield Agreement applications and the administration of Brownfield Agreements.

c) Expenditures may be made from the fund upon requisition by the Executive Director.

d) The fund shall be treated as a special trust fund. Interest earned on the principal shall be credited by the Treasurer to the fund.

e) The fund may receive monies from any available public or private source, including, but not limited to, collection of costs, interest, grants, taxes, public and private donations, judicial actions and appropriated funds.

f) Monies in the fund at the end of the fiscal year shall be retained in the fund for use in the next succeeding fiscal year.

g) All monies collected under this section shall be deposited into the fund.

Chapter 10. HEARINGS AND ENFORCEMENT

Section 1001. Hearings


Any person or interested party aggrieved by any order of MCEQ pursuant to the Act or these regulations may file a request for hearing or notice of appeal pursuant to Miss. Code Ann. Section 49-17-41. Any person who disagrees with any other action of MCEQ pursuant to the Act or these regulations may file a petition with MCEQ for a hearing pursuant to Miss. Code Ann. Section 49-17-35.

Section 1002. Enforcement and Agency Reporting


a) Any material failure of a Brownfield Party or the agents or employees of a Brownfield Party to comply with the Brownfield Agreement constitutes a violation of this section by the Brownfield Party. If a Brownfield Party violates this section, MCEQ may issue an order requiring the Brownfield Party to correct the violation in an appropriate time period established by the order.

b) If the Brownfield Party fails to comply with an order issued under Section 1002(b) or provides false information to MCEQ or MDEQ during the application process or in reports required by the Brownfield Agreement or by state or federal law, MCEQ may remove the liability protection afforded by the Brownfield Agreement under Section 701, require additional remediation, and/or assess civil penalties pursuant to Miss. Code Ann. Section 49-17-43.

c) This section shall not create a defense against the imposition of criminal or civil penalties or other administrative remedies authorized by law for violations of law caused by the Brownfield Party while implementing or failing to implement the Brownfield Agreement.

d) Any land-use restriction or engineering control in a Brownfield Agreement and in a Notice of Brownfield Agreement Site filed under this section may be enforced by MCEQ by initiating an administrative proceeding or by filing a civil action without first having exhausted all available administrative remedies.

e) A land-use restriction or engineering control shall not be declared unenforceable due to lack of privity of estate or contract, due to lack of benefit to particular land, or due to lack of any property interest in particular Brownfield Property within the Brownfield Agreement Site. Any person who owns or leases Brownfield Property within the Brownfield Agreement Site subject to a land-use restriction or engineering control under this section shall abide by the land-use restriction or engineering control.

f) MCEQ may terminate a Brownfield Agreement by order issued pursuant to Section 1002(c). The order shall direct the executive director to issue a notice of cancellation of Brownfield Agreement. Any order to terminate shall provide that all liability protection provided by the Brownfield Agreement has been removed. The statement issued by the executive director shall direct the chancery clerk to make a marginal entry of termination on the Notice of Brownfield Agreement Site and the Brownfield Agreement. In the event a Brownfield Agreement is terminated, the Brownfield Party shall be responsible for notifying the following parties of the termination:

g) Additionally, upon termination the Brownfield Party shall:





SUBPART II

RISK EVALUATION PROCEDURES FOR

VOLUNTARY CLEANUP AND REDEVELOPMENT OF

BROWNFIELD SITES

Chapter 1. GENERAL
Section 101. Introduction
Chapter 2. BROWNFIELD SITE EVALUATION
Section 201. Site Conceptual Exposure Model (SCEM)
Section 202. Criteria For Completing The SCEMs
Section 203. Site Characterization
Section 204. Site Ecological Checklist
Chapter 3. TIER 1 EVALUATION
Section 301. Tier 1 Evaluation Target Risk Level
Chapter 4. TIER 2 EVALUATION
Section 401. Tier 2 Evaluation Target Risk Level
Section 402. Tier 2 Evaluation Options
Chapter 5. TIER 3 EVALUATION
Section 501. Tier 3 Evaluation Target Risk Level
Section 502. Tier 3 Evaluation (Risk Assessment) Procedures
Section 503. Tier 3 Ecological Risk Evaluation Procedures
Chapter 6. RISK-BASED REMEDIATION
Section 601. Risk-Based Remediation Goals
Chapter 7. PETROLEUM HYDROCARBONS
Section 701. Introduction
Section 702. Petroleum Hydrocarbon Evaluation Procedures
Section 703. Tier 1 Petroleum Hydrocarbon Evaluation
Section 704. Tier 2 Petroleum Hydrocarbon Evaluation - TPH Fractioning
Section 705. Tier 3 Petroleum Hydrocarbon Evaluation


SUBPART II. RISK EVALUATION PROCEDURES

Chapter 1. GENERAL

Section 101. Introduction


a) The Mississippi Brownfields Voluntary Cleanup and Redevelopment Program (Brownfields Program) utilizes risk-based criteria for Site evaluation and remediation. The risk-based procedures and rationale for evaluating environmental contamination on or under a Site are presented in this Subpart II. This evaluation is necessary to develop remediation requirements that are protective of human health and the environment. All remediation and/or corrective actions must be approved by MDEQ.

b) In considering the risk-based evaluation of conditions on or under a Site, the following must be addressed:


c) The cornerstone of the Brownfields Program is a three-tiered risk-based process for evaluating human health and environmental risks. These tiers are referred to as Tier 1, Tier 2, and Tier 3. These tiers are designed to allow the Applicant to evaluate and determine appropriate remedial options for site specific conditions. A description of each tier is discussed below.
d) Land use plays an integral role in the three-tiered approach and in the development of the SCEM. Land-use restrictions may reduce or eliminate the potential for exposure to contaminants and risk.

e) Specific criteria for evaluating Sites impacted with petroleum hydrocarbons is contained in Chapter 7 of this Subpart II.

Chapter 2. BROWNFIELD SITE EVALUATION

Section 201. Site Conceptual Exposure Model (SCEM)


a) The SCEM is a graphical representation of actual and potential Site conditions based on available data and an understanding of those Site conditions. A BASELINE and a REMEDIAL SCEM must be completed and are provided in forms prescribed by MDEQ. The BASELINE SCEM represents the risk and exposure conditions that exist prior to the implementation of remediation. The REMEDIAL SCEM represents the risk and exposure conditions that exist or are expected to exist after the implementation of remediation. Items to be identified in the SCEM include the following:

b) Based on the results of the completed BASELINE SCEM, exposure point concentrations (EPCs) must be identified for CoC(s) with completed and potentially completed exposure pathways. EPCs are the concentrations of site-related compounds in a specific media that a human or environmental receptor will contact (Complete) or may potentially contact (Potentially Complete) through ingestion or inhalation at the point of exposure.

c) All four elements identified in the SCEM must be complete for exposure to occur. It is important to note that the BASELINE SCEM should be developed early in the process (i.e., Brownfield Application and/or work plan stage) and identified as "draft" if additional information is pending. The BASELINE SCEM can be updated and modified as the site investigation progresses and more site-specific information becomes available. BASELINE SCEM should be identified as "final" once the Site Characterization is complete.

d) If additional issues of concern pertaining to exposure at the site (additional pathways, media, sources, transport mechanisms, receptors, etc.) are not specifically addressed in the SCEMs, the Applicant should provide an attachment(s) to the appropriate SCEM discussing the additional issues.

e) The BASELINE and REMEDIAL SCEM worksheets must be included as part of the Site Characterization Report and the Corrective Action Report.

f) The procedures for completing the SCEMs follow:

Section 202. Criteria For Completing The SCEMs


a) BASELINE SCEM - The following sections describe the criteria for evaluating the completeness and potential completeness of contaminant exposure for the Site. All potential exposure pathways should be evaluated for completeness, as identified in the SCEM worksheets. The Applicant should provide as much detail as possible. Indicate all sources, transport mechanisms, pathways and receptors that are complete or potentially complete. If information is not available to support a pathway as incomplete then that pathway should be considered to be potentially complete and should be identified for evaluation until such information becomes available. A description of each of the BASELINE SCEM criteria is provided in the following sections.


b) REMEDIAL SCEM - Once the BASELINE SCEM has been completed, remedial options (i.e., institutional controls, engineering controls, or active cleanup) for the Site that can "shut off" or eliminate exposure to contamination should be evaluated. Those complete and potentially complete exposure routes linking sources to receptor populations must be remediated using one or a combination of options. Free product must be remediated in a manner consistent with Section 601(d)(4) of this Subpart II. The REMEDIAL SCEM includes shut-off valves to graphically depict "open" or "closed" pathways between contaminated media and the receptor population. Shut-off valves are marked (shut) to indicate the remedial action that has been taken or proposed for the Site. A description of the types of remedial actions follow:

Section 203. Site Characterization


a) A Site Characterization must be conducted to delineate the nature and extent (vertically and horizontally) of contamination on and under the Site. Site characterization data should be collected and presented in accordance with the Quality Assurance Project Plan (QAPP) and Site Characterization Report formats. In general, the Applicant must demonstrate that the data are representative of the actual and/or potential contamination conditions at the Site. Collected data must include information describing and delineating the contaminant source area. Information pertaining to the characteristics of the CoCs, including the chemical and physical properties as well as the potential of the CoCs to migrate and transport to receptor locations through or in the affected media, must also be provided.

b) The degree of contamination in surface and subsurface soil should be determined by performing soil boring(s) down to the depth of groundwater in the saturated zone. Surface soil is defined as the soil located at the surface and extending to a depth of six (6) feet below the ground surface. The subsurface soil depth is any depth beyond six feet. The Applicant must address ingestion, potential dermal contact, and inhalation (through volatilization and particulates) of hazardous chemicals present in the surface soil. In addition, CoCs in the surface soil may be transported off-site through precipitation runoff.

c) The Applicant must demonstrate that groundwater is not impacted by the site-related contaminant; or that if groundwater is impacted, the impacted groundwater is confined and will remain confined within the Site. Groundwater contaminant concentrations should be determined by collecting groundwater samples.

d) Measured data are those data collected from temporary or permanent (monitoring) wells. The Applicant should install wells, as necessary, to delineate the vertical and horizontal extent of groundwater impact and to determine flow direction and groundwater quality. Wells must be installed, developed, purged, and sampled in a manner consistent with EPA Region IV, Science and Ecological Support Division, Environmental Investigations Standard Operating Procedures and Quality Assurance Manual, May 1996, as amended, or other procedures approved by MDEQ. Measured groundwater data must be based on unfiltered groundwater samples.

e) The site characterization data should be collected in accordance with data quality objectives (DQOs) stipulated in the QAPP. The DQOs shall, at a minimum, identify the number of field and quality control samples, quantitation limits, analytical methods, and sample collection, preservation, and handling methods. Matrix interferences shall be minimized to the extent feasible by modified sample extraction and preparation methods in accordance with EPA or MDEQ approved analytical methodologies.

f) The data collection strategy should be based on the Site Conceptual Exposure Model (SCEM) that hypothesizes or describes how the source chemicals or CoCs are released, transported, and exposed to the receptors.

g) The Applicant must demonstrate that the analytical laboratory data have been reviewed for compliance with the DQOs. In the Site Characterization Report, the Applicant shall identify data that meet DQOs.

h) To establish background chemical concentrations, the Applicant may collect samples from locations, as approved by MDEQ, outside of the influence of known contaminated areas and regionally prevalent chemicals and must analyze these samples using the same analytical methods as the CoC analyses.

i) To establish regionally prevalent chemical concentrations, the Applicant may collect samples from locations, as approved by MDEQ, throughout a substantial geographic region and outside the influence of known contaminated areas and must analyze these samples using the same analytical methods as the CoC analyses.

j) Historical data approved by MDEQ may be submitted in lieu of collecting new data provided that: (1) the Site characterization data requirements are summarized and presented in accordance with the Quality Assurance Project Plan and Site Characterization Report Formats; and (2) the data was collected in a manner consistent with appropriate sampling protocols, as approved by MDEQ. All detailed information must be referenced in the reports including sampling protocols. In any event, relevant previous site characterization reports should be submitted along with the application. Deviations from the required methodologies in the Quality Assurance Project Plan, Site Characterization Report, or Corrective Action Plan formats must be presented to and approved by MDEQ.

Section 204. Site Ecological Checklist


The Ecological Checklist is used to determined if ecological receptors of concern are present and potentially impacted (See Appendix D). If such receptors are present, MDEQ will make a determination as to whether a Tier 3 assessment of ecological risk should be performed to assess the potential ecological impact. Tier 1 and Tier 2 Evaluations are applicable for Sites with no known ecological receptors of concern.

Chapter 3. TIER 1 EVALUATION

Section 301. Tier 1 Evaluation Target Risk Level


The TRGs presented in the Tier 1 TRG table, Appendix A, are based on either (1) a 1x10-6 target risk level for each carcinogenic chemical, (2) a hazard index not to exceed 1 for each systemic toxicant, or (3) constituent TRG concentrations established through federal/state programs (i.e., Safe Drinking Water Act). The values presented in the Tier 1 TRG table will be modified periodically based on EPA updates of toxicity values obtained from the sources presented in Section 502(c)(2) of this Subpart II.

Section 302. Tier 1 Evaluation Procedures


a) The basic methodology for a Tier 1 Evaluation shall be the comparison of the highest concentration of each contaminant in each media to the TRGs provided in the Tier 1 TRG table. Results of the comparison will be used to determine if the site specific data are:


b) Sites that do not require an ecological evaluation beyond the Site Ecological Checklist and that exhibit chemical concentrations that are at or below the unrestricted TRGs do not require further evaluation or action. Such sites are not eligible for the Brownfields Program since remediation is not necessary as required in Section 49-5-5(b) of Mississippi Code Annotated, as amended.

c) Sites with chemical concentrations in soils that are greater than the unrestricted TRGs but below the restricted TRGs may:

d) Sites with chemical concentrations in soils that exceed the restricted TRGs may:

e) Sites with chemical concentrations in groundwater that are greater than the unrestricted TRGs may:

f) MDEQ may consider utilizing the Method Detection Limit (MDL) in place of the Target Remediation Goal (TRG) on a case by case basis.

g) In areas of a site where chemical concentrations of petroleum hydrocarbon indicator compounds (e.g., BTEX, PAHs, MTBE) are not quantifiable to the Tier 1 TRGs (e.g., dilution and/or matrix interference) may:

Chapter 4. TIER 2 EVALUATION

Section 401. Tier 2 Evaluation Target Risk Level


For human health, the remediation goal (RG) for each individual contaminant which is (1) a carcinogen must be calculated to attain a Risk Level of 10-6 (i.e.,1 in a million) and (2) a systemic toxicant must be calculated to attain a total hazard quotient of not more than 1 except with regard to a background chemical concentration or a regionally prevalent chemical concentration. In cases where contaminants with corrective action concentrations established through federal and/or state programs (i.e., Safe Drinking Water Act maximum contaminant levels (MCLs)) are present, the MDEQ will determine the appropriate corrective action concentration on a contaminant by contaminant basis. In no event, except with regard to a background chemical concentration, may either (1) the cumulative (total) site carcinogenic risk exceed 1 x 10-4 for carcinogenic CoCs or (2) the site hazard index (summation of hazard quotients) exceed 3 for non-carcinogenic CoCs affecting the same organ or organ system without the use of both an engineering control and an institutional control.

Section 402. Tier 2 Evaluation Options


a) Tier 2 Evaluation is a more in-depth evaluation of site-specific conditions beyond the Tier 1 Evaluation methodology. The Tier 2 Evaluation may include, but is not limited to, an evaluation of site-specific conditions by (1) determining the Upper Confidence Limit (UCL) of the Mean for a CoC utilizing statistical methods and comparing the UCL to the Tier 1 TRGs, (2) comparing EPCs to calculated background chemical concentrations, (3) comparing EPCs to calculated regionally prevalent chemical concentrations, (4) utilizing site-specific variables (i.e., exposure frequency, exposure duration, etc.) to calculate site-specific RGs, (5) eliminating or minimizing exposure to contaminants, (6) conducting an analysis of Petroleum Hydrocarbons using TPH Fractioning, or (7) utilizing other methods approved by MDEQ.


b) MDEQ may consider utilizing the Method Detection Limit (MDL) as the site-specific Remediation Goal (RG) on a case by case basis.

c) References for any fate and transport models used for the exposure point calculations (EPA-approved model or models that have been peer reviewed by experts in the modeling field) and all input values and assumptions for the models must be provided to and approved by MDEQ.

Chapter 5. TIER 3 EVALUATION

Section 501. Tier 3 Evaluation Target Risk Level


a) Human Health


b) Ecological
Section 502. Tier 3 Evaluation (Risk Assessment) Procedures


a) The Applicant may choose to conduct a site-specific risk assessment (Tier 3), develop and meet site-specific RGs, and have the site-specific RGs approved by MDEQ. This Tier 3 option may entail additional costs to the applicant for MDEQ to subcontract the review of the toxicological and/or risk assessment evaluation. These additional costs shall be paid by the Applicant.

b) For a human health evaluation of the site or areas within the site (if the site characterization data support such area delineations), the Applicant shall perform risk characterization and present information on risk assessment uncertainty in accordance with the following options:

c) The human health evaluation report shall include, at a minimum, four components: hazard identification, toxicity assessment, exposure assessment, and characterization of risk and uncertainty.

d) Non-carcinogens that act on the same organ systems can be identified in Table 2, EPA's Soil Screening Guidance: Technical Background Document (EPA/540/R-95/128) or Appendix A, Tables E, Title 35 Illinois Administrative Code Part 742, as amended. The Applicant must identify the uncertainty associated with each toxicity value. Toxicity values with a high degree of uncertainty should not be used in the risk assessment.

e) The Applicant shall provide information on the CoC exposure point concentrations (EPCs), activities, and exposure routes that lead to exposure. Site-specific information in combination with relevant information found in EPA's Exposure Factors Handbook (Volumes I, II, and III, EPA's National Center for Environmental Assessment, March 1998), AIHC's Exposure Factors Sourcebook, or other peer-reviewed literature approved by MDEQ may be used to assess exposure. At a minimum, the exposure assessment shall include:

f) Carcinogenic risk and non-carcinogenic hazard posed by the CoCs shall be estimated for the Site or areas within the Site where past releases have occurred. Risks from all complete exposure pathways (i.e., incidental ingestion, dermal contact, inhalation of volatiles or particulates), and contaminated on-site food sources (indirect exposure) shall be characterized, as identified in the SCEM.

g) The following risk assessment protocols shall be followed for assessing special chemicals or categories of chemicals, unless otherwise approved by MDEQ:

Section 503. Tier 3 Ecological Risk Evaluation Procedures


a) For the entire Site or areas within the Site (if the site physical characteristics support delineations of different ecosystems), the Applicant shall perform screening and/or more in-depth ecological risk evaluations and present uncertainty associated with the evaluations in accordance with the following options:


b) A deterministic risk evaluation shall include a minimum of four components: problem formulation, ecological effects assessment, exposure assessment, and characterization of risk and uncertainty.

c) A Tier 3 ecological risk evaluation shall be presented in the following report format: problem formulation, approach and rationale, and presentation of results, uncertainties, and recommendations. In interpreting these evaluation findings, the Applicant should consider the effects of natural succession, non-site related impacts (e.g., farm or urban runoff), and seasonal changes on the data or observations collected. The report format may vary based on MDEQ requirements of the ecological risk evaluation work plan.

Section 504. Tier 3 Risk Assessment Data Requirements


a) The basic procedure for the assessment of human health and ecological receptors of concern for a Tier 3 risk assessment shall be to obtain representative site characterization data in order to perform a screening or more in-depth risk assessment. Specific requirements for performing a Tier 3 risk assessment include, but are not limited to, the following:

Chapter 6. RISK-BASED REMEDIATION

Section 601. Risk-Based Remediation Goals


a) Risk-based remediation goals (RGs) may be quantitative for chemical-specific RGs or qualitative for remedial action-specific RGs. The methodology for quantifying the chemical-specific RGs involves solving for the concentration term given a defined risk level in a deterministic or probabilistic risk assessment and shall be proposed for the principal threat chemicals or all CoCs if the principal threat chemicals cannot be identified. The chemical-specific RG may be modified upward or downward based on risk management considerations by MDEQ. A qualitative RG is established by describing the objectives for engineering controls that reduce site risk to an acceptable level. Risk-based remediation goals shall accompany the proposed remedial action(s) in the Site Characterization Report and/or the Corrective Action Plan (CAP).

b) Quantitative RG - Site-specific information that is relevant to the future use of the Site shall be used in the risk methodology.


c) Qualitative RG - A qualitative RG shall define objectives and describe how land-use restrictions and/or engineering controls are expected to reduce site risk to an acceptable level. The following information shall be presented:
d) No further action at the Site shall be based on obtaining either the quantitative or qualitative RGs, or both, and/or other terms and conditions stipulated by MDEQ (i.e., Brownfield Agreement, Corrective Action Plan). The Applicant has the option to propose either type of RGs or a combination of the two for delineated areas of the Site, depending on the site-specific factors, chemical data, and risk management considerations approved by the MDEQ. The following criteria shall be met for this determination:
Chapter 7. PETROLEUM HYDROCARBONS

Section 701. Introduction


a) Specific procedures and evaluation criteria have been developed for sites with petroleum hydrocarbon contamination. This criteria has been developed to simplify the contaminant analyses required to characterize the site and to establish site-specific remediation goals (RGs). Petroleum hydrocarbon indicator compounds (i.e., Benzene, Toluene, PAHs, etc.) may not be quantifiable at the Tier 1 TRG Table concentrations because high petroleum hydrocarbon concentrations in the sample may cause analytical interferences resulting in either of the following:


b) In addition, of the 250 individual compounds identified in petroleum, only 95 have toxicity data. Of these 95 compounds with toxicity data, only 25 have sufficient data to develop toxicity criteria. The interactive effects of all compounds present in TPH cannot be determined by data on 25 individual compounds. Therefore, to account for these unknowns, as well as to account for instances as described in Section 701(a), these procedures have been developed.

c) To evaluate human health and environmental risks specific to a Site under the circumstances in Section 701(a)(1) and (2), MDEQ has developed procedures for petroleum hydrocarbon contaminated Sites.

Section 702. Petroleum Hydrocarbon Evaluation Procedures


a) The Applicant shall utilize the procedures presented herein for the evaluation of potential human health and environmental risks from petroleum hydrocarbons in soil and groundwater.

b) A Tier 1 Evaluation of indicator compounds of petroleum hydrocarbons and TPH is required to establish the vertical and horizontal extent of indicator compound concentrations and TPH below the unrestricted values of the Tier 1 TRG Table.

c) A Site Ecological Checklist must be completed.

d) Petroleum-impacted soil and groundwater shall be assessed using the petroleum hydrocarbon indicator compounds, TPH-GRO, and TPH-DRO as presented in Appendix B, Table 1. Petroleum hydrocarbon categories presented in Appendix B, Table 1 represent typical hydrocarbon products. The Applicant shall correlate the site-specific hydrocarbon release and/or knowledge of the released hydrocarbon product to the appropriate category listed in Appendix B, Table 1. If the specific product that has been released is unknown, then a complete analytical evaluation must be conducted.

e) The Applicant shall perform soil and groundwater laboratory testing for the following indicator compounds:


f) Although lead (organic and inorganic) has not been used as a gasoline additive for some time (since the late 1970's to early 1980's), there may be sites where lead (organic and inorganic) may be present due to historical activities on the Site. At sites where lead is suspected to be present as a potential site-related compound, inorganic lead and organic lead (specifically tetraethyl lead) must be identified as target analytes by appropriate analytical methods approved by MDEQ.

Section 703. Tier 1 Petroleum Hydrocarbon Evaluation


a) A Tier 1 Evaluation of indicator compounds of petroleum hydrocarbons, TPH-GRO, and TPH-DRO is required to establish the extent of indicator compound concentrations and TPH-GRO/DRO below the Tier 1 TRG Table.

b) Results of the indicator compound analysis, TPH-GRO, and TPH-DRO shall be compared with the TRGs presented in the Tier 1 TRG Table in Appendix A utilizing the Tier 1 Evaluation Procedures outlined in Section 302 of this Subpart II.

c) The Applicant shall address a hydrocarbon release using TPH analyses using SW-846 Method 8015B or other Method approved by MDEQ and by analyzing the indicator compounds as described in Section 701.

d) In areas of the site where the indicator compounds cannot be quantified to the Tier 1 Target Remedial Goal concentrations, the Applicant has the option of either:

Section 704. Tier 2 Petroleum Hydrocarbon Evaluation - TPH Fractioning


a) A Tier 2 Petroleum Hydrocarbon Evaluation is primarily utilized in cases as described in Section 701 of this Subpart II where indicator compound concentrations cannot be determined due to dilution and interference and where the concentrations of TPH-GRO/DRO exceed the restricted Tier 1 TRG levels for TPH-GRO/DRO. Along with the required comparison of indicator compounds as described in Section 703(b) of this Subpart II, the Applicant shall have the option of utilizing the TPH Carbon Fraction TRGs in Table 2 of Appendix B.

b) Massachusetts Method



Toxicological Approach for Non-Carcinogens
Hydrocarbon
Fraction
Analytical
Fraction
Analytical
Method
Surrogate
Compound
Reference Dose
(mg/kg/d)
C5-C8
Aliphatics
C5-C8VPHn-Hexane0.06
C9-C18
Aliphatics
C9-C12
C9-C18
VPH
EPH
n-Nonane
n-Nonane
0.06
0.06
C19-C36
Aliphatics
C19-C36EPHEicosane6.0
C9-C22
Aromatics
C9-C10
C11-C22
VPH
EPH
Pyrene
Pyrene
0.03
0.03

c) MDEQ may approve other TPH risk evaluation methodologies (e.g., TPHWG Methodology) or combinations thereof under Tier 2.

Section 705. Tier 3 Petroleum Hydrocarbon Evaluation


a) Alternative petroleum hydrocarbon Remedial Goals (RGs) may be established using a Tier 3 Risk Assessment approach. The alternative RGs shall be reviewed and approved or disapproved by MDEQ on a case-by-case basis.

References

American Society for Testing and Materials (ASTM), Standard Guide for Risk-Based Corrective Action Applied at Petroleum Release Sites (ASTM E 1739-95), 1995.

Agency for Toxic Substances and Disease Registry (ATSDR), Toxicological Profile for Mineral Oil Hydraulic Fluids, Organophosphate Ester Hydraulic Fluids, and Polyalphaolefin Hydraulic Fluids, 1994.

Massachusetts Department of Environmental Protection, Characterizing Risk posed by Petroleum Contaminated Sites: Implementation of MADEP VPH/EPH Approach, 1996.

Louisiana Department of Environmental Quality, April 1998, Risk Evaluation/Corrective Action Program (Proposed), April 1998.

U.S. Environmental Protection Agency (EPA), Handbook of RCRA Ground-Water Monitoring Constituents, Chemical and Physical Properties, 40 CFR Part 264, Appendix 9. September 1992.

U.S. Environmental Protection Agency (EPA), Soil Screening Guidance: Technical Background Document (EPA/540/R-95/128), May 1996.

U.S. Environmental Protection Agency (EPA), Supplemental Guidance to RAGS: Calculating the Concentration Term, EPA 1992, 9285.7-081 (EPA, 1992a).







APPENDIX A

TIER 1 TARGET REMEDIAL GOAL TABLE

Notes




APPENDIX B

PETROLEUM HYDROCARBON TABLES

TABLE 1

PETROLEUM HYDROCARBON INDICATOR COMPOUNDS1

Type of Release
Indicator CompoundGasolineKerosene, Jet FuelDiesel, Light Fuel OilsHeavy Fuel OilsCrude OilHighly Refined Base Oils2Used Motor Oil, Lubricating OilUnknown
T
TPH-GRO
XXX
TPH-DROXXXXXXX
VolatilesXXX
AcenaphtheneXXXXXXX
AcenaphthyleneXXXXXXX
AnthraceneXXXXXXX
Benz[a]anthraceneXXXXXXX
Benzo[a]pyreneXXXXXXX
Benzo[b]fluorantheneXXXXXXX
Benzo[g,h,i]peryleneXXXXXXX
Benzo(k)fluorantheneXXXXXXX
ChryseneXXXXXXX
FluorantheneXXXXXXX
FluoreneXXXXXXX
Indeno[1,2,3-c,d]pyreneXXXXXXX
2-MethylnaphthaleneXXXXXXX
NaphthaleneXXXXXXX
PhenanthreneXXXXXXX
PyreneXXXXXXX
MetalsXX
Methyl tertbutyl etherXX
Methyl ethyl ketoneX3X
Methyl isobutyl ketoneX3X

NOTES:


TABLE 2

TIER 2 PETROLEUM HYDROCARBON
TARGET REMEDIATION GOALS (TRGS)

Carbon
Fraction
MethodGroundwater
(ėg/L)
Soils
Unrestricted
(mg/kg)
Soils
Restricted
(mg/kg)
C5-C8Aliphatic400100500
C9-C12Aliphatic4,0001,0005,000
C9-C10Aromatic200100100
C9-C18Aliphatic2001005,000
C19-C36Aliphatic5,0002,5005,000
C11-C22Aromatic200200200
































ECOLOGICAL CHECKLIST


MISSISSIPPI DEPARTMENT OF ENVIRONMENTAL QUALITY
BROWNFIELD VOLUNTARY CLEANUP PROGRAM
ECOLOGICAL CHECKLIST

Section I- Facility Information

1.Name of Facility:
2.Location of Facility:
County:
3.Mailing Address:
4.Type of Facility:
5.Describe land use at and in the vicinity of the release site
6.Attach a USGS topographic map of the facility and aerial and other photographs of the release site and surrounding areas.
Section 2-Surrounding Land Use Information

1.Describe land use adjacent to the facility.
2.Provide the following information regarding the nearest water body:
Name of surface water body:
Type of surface water body (pond, lake, river etc:
3.Do any potentially sensitive environmental areas exist adjacent to or in proximity to the site, e.g., Federal and State parks, National and State Monuments, wetlands, etc.
Section 3 - Release Information

1.Nature of release.
2.Location of the release (within the facility)
3.Location of the release with respect to the facility property boundaries:
4.Chemicals of Concern (COC) known or suspected to have been released:
5.Indicate which media are known or suspected to be impacted and if sampling data are available:
Soil 0-6 feet bgsyesno
groundwateryesno
surface water/sedimentyesno
6.Has migration occurred outside the facility property boundaries?yesno
If yes, describe the designated use of the land impacted:

Section 4 - Criteria for Further Assessment

If the Area of Impact (AOI) meets all of the criteria presented below, then typically no further ecological evaluation shall be required. If the AOI does not meet all of the criteria, then a screening level ecological risk shall be conducted. The Submitter should make the initial decision regarding whether or not a screening level ecological risk assessment is warranted based on compliance of the AOI with criteria listed below. After review of the ecological checklist and other available site information, the Mississippi Department of Environmental Quality will make a final determination on the need for a screening level ecological risk assessment. If site conditions at the AOI change such that one or more of the criteria are not met, then a screening level ecological risk assessment shall be conducted.

The criteria for exclusion from further ecological assessment include:

The area of impacted soil is approximately 1 acre or less in size;

Section 5 - Site Summary

Section 6 - Submitter Information
Date:
Name of person submitting this check list:
Affiliation:
Signature
Additional Preparers: